Please use this identifier to cite or link to this item:
Title: Synthesis and X-Ray Crystal Structure of [(thf)4Ca{Fe2(CO)6(µ-CO)(µ-PPh2)}2]
Authors: Tareq Mousa Ali Al-Shboul, Helmar G?rls, Matthias Westerhausen*
Issue Date: 1983
Publisher: Deanship of Research and Graduate Studies , Yarmouk University, Irbid , Jordan
Description: The reaction of [(thf)4Ca(PPh2)2] with iron carbonyls such as Fe(CO)5, Fe2(CO)9, and Fe3(CO)12 yields the heterobimetallic contact ion pair [(thf)4Ca{Fe2(CO)6(µ-CO)(µ-PPh2)}2] as shown below. The hexa-coordinate calcium atom binds to the bridging carbonyl groups of the dinuclear anions. The reaction proceeds via two main intermediates which are observed by NMR spectroscopy.
Appears in Collections:Journal of Chemistry

Files in This Item:
File SizeFormat 
Vol4No2-2.pdf349.36 kBAdobe PDFView/Open

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.