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Title: Adduct Formation and Stability of Methyltrioxorhenium(VII) with a Series of Aliphatic and Aromatic Nitrogen Donor Ligands
Authors: Mazin Y. Shatnawi* and Ahmad M. Al-Ajlouni*
Issue Date: 1983
Publisher: Deanship of Research and Graduate Studies , Yarmouk University, Irbid , Jordan
Description: Aliphatic and aromatic N-donor ligands form 1:1 adducts with the well known catalyst; methyltrioxorhenium(VII), MTO, in organic solvents. The formation constant (Kf) is correlated well with the pKa value of the ligand, and increases with the ligands' basicity. In general, the aromatic ligand adducts are much more stable than the aliphatic ones.
Appears in Collections:Journal of Chemistry

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